Diaquadichloridomethylphenyltin(IV)–1,4,7,10,13-pentaoxacyclopentadecane (1/1)
نویسندگان
چکیده
The asymmetric unit of the title cocrystal, [Sn(CH(3))(C(6)H(5))Cl(2)(H(2)O)(2)]·C(10)H(20)O(5), contains two independent for-mula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water-crown ether O-H⋯O hydrogen bonds into a linear chain running along [101]. Each coordinated water mol-ecule forms a pair of hydrogen bonds to the same crown ether; for the crown ether mol-ecules, only four of the five O atoms are engaged in hydrogen-bonding inter-actions. The metal ions show a distorted trans-C(2)SnCl(2)O(2) octa-hedral coordination geometry [C-Sn-C = 175.3 (1) and 178.9 (1)°].
منابع مشابه
Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1)
The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal-bipyramidal coordination [C-Sn-C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a tin-chlorine bridge [Sn←Cl = 3.247 (1) Å] across a center of inversion, generating a dinuclear sp...
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